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Meta Chloroaniline (3-Chloroaniline) | CAS 108-42-9 | Chelora Dyes
Chelora Dyes / Product SpecimenCAS 108-42-9
Diazo component

Meta Chloroaniline

A simple monochlorinated aromatic amine, supplied as 3-chloroaniline for use as a diazo component across dye intermediate manufacture.

CAS 108-42-9 C6H6ClN Assay ≥ 98% 127.57 g/mol
ColourlessFresh material
Pale yellowTypical liquid lot
AmberAged / stored material
Overview01

What is Meta Chloroaniline?

Meta Chloroaniline, formally 3-chloroaniline, is a clear pale yellow to brown liquid built on a benzene ring carrying a primary amine at C-1 and a single chlorine atom at the meta C-3 position.

That simple substitution pattern is what makes the molecule such a versatile building block. The amine diazotises readily under standard acidic conditions, and the meta chlorine gives the resulting diazonium salt clean, predictable coupling behaviour, making it a dependable diazo component for azo dye and pigment chemistry.

At Chelora Dyes, Meta Chloroaniline is distilled and packed under controlled conditions to a consistent colour and low moisture, so diazotisation and coupling reactions downstream run cleanly and give consistent, reproducible results batch to batch.

Appearance
Pale yellow to brown liquid
Odour
Characteristic amine
Solubility
Acetone, ether, ethanol
Function
Diazo component
Grade
Technical / dye
Molecular structure02
1 2 3 4 5 6 NH2 Cl NH2 at C-1 · Cl at C-3

Meta-substituted chloroaniline

  • Molecular formulaC6H6ClN
  • Molecular weight127.57 g/mol
  • IUPAC name3-Chloroaniline
  • Functional groupsAromatic amine, aryl chloride
  • CAS number108-42-9
Specifications03

Technical product information

Standard specification for Chelora Dyes' technical grade Meta Chloroaniline. Custom-grade and bulk specifications are available on request.

Chemical nameMeta Chloroaniline
Synonyms3-Chloroaniline, m-Chloroaniline, MCA
CAS number108-42-9
Molecular formulaC6H6ClN
Molecular weight127.57 g/mol
Assay (purity)≥ 98.0%
AppearanceClear, pale yellow to brown liquid
Melting point−11 to −9°C
Boiling point230–231°C
Moisture content≤ 0.5%
SolubilitySlightly soluble in water; miscible with acetone, ether and ethanol
Packaging25 kg / 200 kg drums, IBC totes for bulk
Shelf life24 months in sealed original packaging
Applications04

Applications of Meta Chloroaniline

Azo dye diazo component

Diazotised and coupled with phenolic or amine partners to build azo dye chromophores.

Pigment intermediates

A common building block feeding a range of organic pigment intermediates.

Dye & pigment chemistry

Feeds intermediates used across dye, pigment and specialty colourant manufacture.

Pharmaceutical intermediates

Used as a starting material in select pharmaceutical and fine chemical synthesis routes.

Analytical reagents

Used as a reference reagent in analytical and laboratory-scale synthesis work.

Custom synthesis

Supplied to order for custom manufacturing and contract synthesis projects.

The Chelora standard05

Why choose Chelora Dyes

Consistent purity

Assay controlled at ≥98% with moisture and colour verified before dispatch.

Full documentation

COA, SDS, and regulatory data supplied with every shipment.

Flexible volumes

From 25 kg drums to bulk IBC tote quantities.

Technical support

Process, diazotisation, and compliance guidance from our chemistry team.

Handling06

Storage and guidelines

  • Store in tightly sealed original containers, protected from light.
  • Keep below 30°C, in a cool, dry, well-ventilated area.
  • Store under inert gas where practical, as the material darkens on air exposure.
  • Segregate strictly from strong oxidising agents.
  • Use compatible containers: lined steel or HDPE drums.
  • Re-seal containers promptly after use to preserve assay specification.

Handling precautions

Meta Chloroaniline is classified as toxic by inhalation, in contact with skin and if swallowed, with aquatic toxicity; contact should be strictly avoided.

Use closed handling equipment, vapour extraction, and full PPE including chemically resistant gloves, goggles and, where indicated by the risk assessment, respiratory protection during transfer, charging and any bulk handling operation.

Keep away from strong oxidisers and sources of ignition.

Refer to the full Safety Data Sheet for exposure limits, spill containment, disposal, and first-aid measures before use.

Support07

Frequently asked questions

What is Meta Chloroaniline used for?

Meta Chloroaniline is used as a diazo component in the synthesis of azo dyes and pigments, and as a general aromatic amine intermediate in agrochemical and pharmaceutical synthesis.

Why is the amine on this molecule useful for diazotisation?

As a simple primary aromatic amine with a single meta chlorine, it diazotises readily and predictably under standard acidic conditions, giving a diazonium salt suited to azo coupling.

Is Meta Chloroaniline soluble in water?

It is only slightly soluble in water. It is miscible with common organic solvents such as acetone, ether and ethanol, which is why it is normally handled and reacted in an organic or mixed solvent system.

What purity do you supply?

Standard technical grade is supplied at a minimum assay of 98%, with moisture and colour held within tight limits. Higher assay grades can be manufactured to order.

What packaging is available for a liquid intermediate like this?

25 kg and 200 kg lined steel or HDPE drums, with bulk supply available in IBC totes for larger volumes.

How should it be stored, and for how long?

In sealed original containers below 30°C, under inert gas where practical and protected from light, away from strong oxidising agents. Shelf life is 24 months from manufacture when storage conditions are maintained.

Is it hazardous to handle?

It is classified as toxic by inhalation, in contact with skin and if swallowed, with aquatic toxicity, and must be handled strictly according to its Safety Data Sheet, with closed handling, dedicated PPE and adequate ventilation.

Do you provide a Certificate of Analysis?

Yes. Each batch ships with a Certificate of Analysis and Safety Data Sheet covering assay, moisture, appearance and boiling range.